|
|
1alpha(S)-6-O-methyl-N-deacetylisoipecoside + H2O <=> 1alpha(S)-6-O-methyl-N-deacetylisoipecoside_aglycone + D-glucose
|
3.2.1
3.2.1.B16
|
–
–
|
|
BRENDA:
BS416057
KEGG:
R11682
MetaCyc:
RXN-13791
|
|
|
|
dopamine + secologanin <=> H2O + N-deacetylisoipecoside
|
4.3.3.3
deacetylisoipecoside synthase
|
–
|
|
BRENDA:
BR26150
KEGG:
R05750
MetaCyc:
4.3.3.3-RXN
|
|
|
|
dopamine + Protoemetine <=> 7''-O-demethylcephaeline + H2O
|
not assigned
|
–
|
|
KEGG:
R11684
MetaCyc:
RXN-13794
|
|
|
|
S-adenosyl-L-methionine + cephaeline <=> emetine + S-adenosyl-L-homocysteine + H+
|
2.1.1
2.1.1.B83
2.1.1.B84
|
–
–
–
|
|
BRENDA:
BR49878
KEGG:
R11686
MetaCyc:
RXN-13796
|
|
|
|
S-adenosyl-L-methionine + 7''-O-demethylcephaeline <=> cephaeline + S-adenosyl-L-homocysteine + H+
|
2.1.1
2.1.1.B83
2.1.1.B85
|
–
–
–
|
|
BRENDA:
BR49877
KEGG:
R11685
MetaCyc:
RXN-13795
|
|
|
|
6,7-O,O-dimethyl-N-deacetylisoipecoside_aglycon <=> Protoemetine
|
not assigned
|
–
|
|
MetaCyc:
RXN-13793
|
|
|
|
S-adenosyl-L-methionine + 1alpha(S)-6-O-methyl-N-deacetylisoipecoside_aglycone <=> 6,7-O,O-dimethyl-N-deacetylisoipecoside_aglycon + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
|
MetaCyc:
RXN-13792
|
|
|
|
S-adenosyl-L-methionine + N-deacetylisoipecoside <=> 1alpha(S)-6-O-methyl-N-deacetylisoipecoside + S-adenosyl-L-homocysteine + H+
|
2.1.1
2.1.1.B84
|
–
–
|
|
BRENDA:
BS419557
KEGG:
R11681
MetaCyc:
RXN-13790
|
|